関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dimethylformamide | HCID 6228 | — |
| 反応物 | 4-Formylbenzoic acid | HCID 12088 | — |
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 4-Formylbenzoyl chloride | HCID 12424620 | — |
反応手順
A solution of 4-carboxybenzaldehyde (30.0 g, 0.200 mol) in toluene (300 mL) was treated with thionyl chloride (28.6 g, 0.240 mol) and DMF (1.0 mL). The reaction mixture was heated at 100° C. for 2 h, during which time the solids dissolved to yield a pale yellow colored solution. The reaction mixture was cooled to 0° C. to yield a solution of the title compound in toluene, which was used without further manipulation.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07728129B2 |
|---|
| 出典データセット | uspto-grants-2010_06 |
|---|
| ORD ID | ord-abc6f75142d542af8371fa9c0841d003 |
|---|
| 出典メモ | uspto-grants-2010_06 |
|---|
