Hexachloroacetone → tert-butyl N-(4-chlorocyclohex-2-en-1-yl)carbamate

反応式

[Cl:35][C:36]([Cl:37])([Cl:38])[C:39]([C:40]([Cl:41])([Cl:42])[Cl:43])=[O:44].[OH:1][CH:2]1[CH:3]=[CH:4][CH:5]([NH:8][C:9](=[O:10])[O:11][C:12]([CH3:13])([CH3:14])[CH3:15])[CH2:6][CH2:7]1.[c:16]1([P:17]([c:18]2[cH:19][cH:20][cH:21][cH:22][cH:23]2)[c:24]2[cH:25][cH:26][cH:27][cH:28][cH:29]2)[cH:30][cH:31][cH:32][cH:33][cH:34]1>>[CH:2]1([Cl:35])[CH:3]=[CH:4][CH:5]([NH:8][C:9](=[O:10])[O:11][C:12]([CH3:13])([CH3:14])[CH3:15])[CH2:6][CH2:7]1

参加物

反応物 3

HCID 8303Hexachloroacetone

HCID 11776Triphenylphosphine

HCID 132943722-Methyl-2-propanyl (4-hydroxy-2-cyclohexen-1-yl)carbamate

生成物 1

HCID 69157617tert-butyl N-(4-chlorocyclohex-2-en-1-yl)carbamate

出典と根拠

ORDレコード: ord-43435de11c54482e9b2160cdb3e8060f
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…