1-Bromohexane → HCID 11732181、化合物

HRID 1358062ノート

反応式

HRID 1358062 の反応式
[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

参加物

3

反応物 2

HCID 81011-BromohexaneHCID 2519872,7-Dichlorofluorene

生成物 1

HCID 11732181HCID 11732181、化合物収率 91%

実験手順

2,7-Dichloro-9,9-di(l-hexyl)fluorene was prepared from 2,7-dichlorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield; melting point 66° C. to 67° C. HPLC analysis showed that the sample was 99 percent or greater pure and the spectral data confirmed the title structure.

後処理

  1. customas colorless crystals (recrystallized from hexane) in 91 percent yield

出典と根拠

ORDレコード
ord-adbe979421204758897b7f3233f77017
出典データセット
uspto-grants-2003_07
特許番号
US06593450B2

反応ノート

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