関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 2-Nitrophenol | HCID 6947 | — |
| 反応物 | Benzyl Chloride | HCID 7503 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | Benzyl-2-nitrophenyl Ether | HCID 57359178 | — |
反応手順
A mixture of 2-nitrophenol (27.82 g˜0.18 mol, Lancaster, contains ca 10% H2O), K2CO3 (33.15 g, 0.24 mol), and benzyl chloride (30.38 g, 27.6 ml, 0.24 mol) was heated at 100° C. for 1.5 h. The resulting mixture was poured in 1.3 L of water and extracted with CHCl3 tree times, washed twice with 50% brine, dried with Na2SO4, filtered and concentrated. Distillation in vacuum gave 39.23 g (96%), bp 161-162° C. (˜0.1 mm Hg).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06596734B1 |
|---|
| 出典データセット | uspto-grants-2003_07 |
|---|
| ORD ID | ord-3f1355235afc4195a10996996216cf34 |
|---|
| 出典メモ | uspto-grants-2003_07 |
|---|
