Oxalic Acid → 2-[4-(4-Isopropoxymethyl-benzyl)-phenyl]-imidazoline oxalate
反応式
[C:1]([OH:6])(=[O:5])[C:2]([OH:4])=[O:3].[CH:7]([O:10][CH2:11][C:12]1[CH:29]=[CH:28][C:15]([CH2:16][C:17]2[CH:22]=[CH:21][C:20]([C:23]3[NH:24][CH2:25][CH2:26][N:27]=3)=[CH:19][CH:18]=2)=[CH:14][CH:13]=1)([CH3:9])[CH3:8]>>[C:1]([OH:6])(=[O:5])[C:2]([OH:4])=[O:3].[CH:7]([O:10][CH2:11][C:12]1[CH:29]=[CH:28][C:15]([CH2:16][C:17]2[CH:22]=[CH:21][C:20]([C:23]3[NH:27][CH2:26][CH2:25][N:24]=3)=[CH:19][CH:18]=2)=[CH:14][CH:13]=1)([CH3:9])[CH3:8]参加物
3
実験手順
Oxalic acid (129 mg, 1.43 mmol) was added to 2-[4-(4-isopropoxymethyl-benzyl)-phenyl]-imidazoline and recrystallized from acetone to give 2-[4-(4-isopropoxymethyl-benzyl)-phenyl]-imidazoline oxalate (507 mg) as a white crystalline solid, m.p. 156.3-156.7° C.; Analysis for C20H25N3O•C2H2O4: Calc.: C, 63.91; H, 6.58; N, 10.16; Found: C, 63.98; H, 6.53; N, 10.24.
後処理
- customrecrystallized from acetone
出典と根拠
- ORDレコード
- ord-62ae14cc4fe442a993711df1610c51cc