Toluene → manganese(2+) neodecanoate

HRID 1358895ノート

反応式

HRID 1358895 の反応式
[O-]S([O-])(=O)=O.[Mn+2:6].O.C1(C)C=CC=CC=1.[C:15]([O-:26])(=[O:25])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([CH3:24])([CH3:23])[CH3:22].[Na+]>O>[C:15]([O-:26])(=[O:25])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([CH3:22])([CH3:23])[CH3:24].[Mn+2:6].[C:15]([O-:26])(=[O:25])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([CH3:22])([CH3:23])[CH3:24]

参加物

5

反応物 3

HCID 1140TolueneHCID 177577Manganese sulfate monohydrateHCID 236891301135294-90-4

生成物 1

HCID 22315822manganese(2+) neodecanoate

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Manganese neodecanoate was prepared by the following procedure: 8.45 g (0.05 moles) of MnSO4.H2O was dissolved in 50 g of water. 50 ml of toluene was added, and with vigorous stirring 77.6 g of a 25% solution of sodium neodecanoate (0.1 moles) was added in about 10 minutes. Rapid stirring was continued for 10 minutes after the addition was complete, stirring was discontinued, and the mixture was allowed to stand for 10 minutes to separate to a dark red organic phase and a clear colorless water phase. The organic phase weighed 87 g and contained 25% manganese neodecanoate, which after removing the solvent by evaporation was a dark red viscous liquid with viscosity>200,000 cps.

後処理

  1. additionwas added in about 10 minutes
  2. additionafter the addition
  3. stirringstirring
  4. waitto stand for 10 minutes
  5. customto separate to a dark red organic phase
  6. customafter removing the solvent
  7. customby evaporation

出典と根拠

ORDレコード
ord-6fc9b236a9d04917b0f98a1f73f21de8
出典データセット
uspto-grants-2003_07
特許番号
US06599472B1

反応ノート

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