Methanethiol → N-acetyl-L-methionine
反応式
[C:1]([NH:4][CH:5]1[CH2:10][CH2:9][O:8][C:6]1=[O:7])(=[O:3])[CH3:2].[CH3:11][SH:12]>>[C:1]([NH:4][C@H:5]([C:6]([OH:8])=[O:7])[CH2:10][CH2:9][S:12][CH3:11])(=[O:3])[CH3:2]参加物
3
実験手順
Subsequently the N-acetyl-2-aminobutyrolactone (1 eq) was reacted with various bases in MeSH to give N-acetylmethionine. A mixture of N-acetylaminolactone, base and MeSH (14 eq) was heated in a sealed autoclave. After cooling, expansion and removal of MeSH, the remaining oil was analysed by HPLC. Further details and the yield of N-acetyl-L-methionine achieved are listed in the table below:
出典と根拠
- ORDレコード
- ord-e392f12332cf4a6c8aecb908f1595fdc
- 出典データセット
- uspto-grants-2011_02
- 特許番号
- US07884240B2
反応ノート
読み込み中…