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Water → 2,2-diethoxyethyl Benzoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Dimethylformamide | HCID 6228 | — |
| 反応物 | 2-Chloro-1,1-diethoxyethane | HCID 12128 | — |
| 反応物 | Potassium Benzoate | HCID 23661960 | — |
| 溶媒 | Ethyl Acetate | HCID 8857 | — |
| 生成物 | 2,2-diethoxyethyl Benzoate | HCID 11817258 | 30% |
反応手順
Chloroacetaldehyde diethyl acetal (1.9 g), potassium benzoate (2.0 g) and DMF (20 mL) were placed in a three-neck flask, followed by refluxing. Twenty hours later, the reaction mixture was cooled to room temperature, and water (60 mL) and ethyl acetate (80 mL) were added thereto, followed by stirring. After filtration and separation, the organic layer was concentrated and thereby yielded the target compound (0.69 g) in a yield of 30%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07728152B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-ab04dd03fbe84d7fa44f135c7f0202f5 |
| 出典メモ | uspto-grants-2010_06 |