関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | Methacryloyl chloride | HCID 13528 | — |
| 反応物 | 2-Ethyl-2-adamantanol | HCID 4401951 | — |
| 溶媒 | Methyl Isobutyl Ketone | HCID 7909 | — |
| 生成物 | 2-Ethyl-2-methacryloyloxyadamantane | HCID 9813645 | 60% |
反応手順
180 g of 2-Ethyl-2-adamantanol, 303 g of triethylamine and 500 g of methylisobutyl ketone were mixed by stirring at 90° C. While stirring, 157 g of methacrylic acid chloride was added dropwise to the mixture. After completion of the dropwise addition, the mixture was further stirred for 72 hours. Then, extraction and distillation were conducted to obtain 2-ethyl-2-adamantyl methacrylate at the yield of 60%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06579659B2 |
|---|
| 出典データセット | uspto-grants-2003_06 |
|---|
| ORD ID | ord-9a8617f7ceab4cba9d7d1e46a274944a |
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| 出典メモ | uspto-grants-2003_06 |
|---|
