ホームMCPワークベンチSkills
ホームワークベンチ通知マイページ
llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.8.0
  1. ホーム
  2. /反応

Diethyl Ether → N-isobutyl-2,3,4,5-tetraphenylcyclopentadieneimine

HRID 1371232
ノート
印刷プレビュー

反応式

HRID 1371232 の反応式
[C:1]1([C:7]2[C:11](=O)[C:10]([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)=[C:9]([C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)[C:8]=2[C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:31]([NH2:35])[CH:32]([CH3:34])[CH3:33].C(OCC)C>C1(C)C=CC=CC=1.Cl[Ti](Cl)(Cl)Cl>[CH2:31]([N:35]=[C:11]1[C:10]([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:9]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[C:8]([C:25]2[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=2)=[C:7]1[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH:32]([CH3:34])[CH3:33]
参加物実験手順後処理出典と根拠反応ノート

参加物

6

反応物 3

HCID 3283Diethyl EtherHCID 6558IsobutylamineHCID 680682,3,4,5-Tetraphenyl-2,4-cyclopentadien-1-one

生成物 1

HCID 22247244N-isobutyl-2,3,4,5-tetraphenylcyclopentadieneimine収率 67.1%

試薬・触媒・溶媒 2

HCID 24193Titanium Tetrachloride触媒HCID 1140
Toluene
溶媒

実験手順

3 g (7.8 mmol) of tetraphenylcyclopentadienone and 3.49 ml (35.1 mmol) of isobutylamine were dissolved in 50 ml of toluene and 0.7 ml (5.85 mmol) of TiCl4 was added thereto at 0° C. The resulting mixture was agitated for 30 minutes at room temperature and then refluxed for 12 hours. The reaction mixture was cooled and diethyl ether was added thereto to induce solid precipitation. The resultant solid was filtered and dried to obtain 2.3 g of the title compound.

後処理

  1. customat 0° C
  2. temperaturerefluxed for 12 hours
  3. temperatureThe reaction mixture was cooled
  4. customsolid precipitation
  5. filtrationThe resultant solid was filtered
  6. customdried

出典と根拠

ORDレコード
ord-0cfc34e8472b4625acb616697f40a1d3
出典データセット
uspto-grants-2007_01
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US07156731B2

反応ノート

読み込み中…

このページの内容参加物実験手順後処理出典と根拠反応ノート