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Isopropenyl acetate → (+)-Styrallyl acetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Isopropenyl acetate | HCID 7916 | — |
| 反応物 | 4-Chlorophenyl Acetate | HCID 13410 | — |
| 生成物 | (+)-Styrallyl acetate | HCID 6951704 | 95% |
反応手順
The procedure of Example 1 was repeated except that 3 molar equivalents of p-chlorophenyl acetate (a conventional acylating agent) was used in place of isopropenyl acetate in the presence of three times the amount of the enzyme catalyst used in Example 1 over a reaction period of 42 hours, to obtain (R)-1-phenylethyl acetate having an optical purity of higher than 99%, at a yield of 95%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07156731B2 |
| 出典データセット | uspto-grants-2007_01 |
| ORD ID | ord-1bc0273f6d9e4898b5a2d888224182f6 |
| 出典メモ | uspto-grants-2007_01 |