Cyclen tetrahydrochloride → 1,4,7,10-Tetraazacyclododecane

HRID 1372797ノート

反応式

HRID 1372797 の反応式
[CH2:1]1[NH:12][CH2:11][CH2:10][NH:9][CH2:8][CH2:7][NH:6][CH2:5][CH2:4][NH:3][CH2:2]1.Cl.Cl.Cl.Cl.C1N2C(=O)N3C4N5C(=O)N(CN6C(N7CN8C(N9CN%10C(N%11CN%12C(N%13CN%14C(N%15CN%16C(N%17CN%18C(N(C5)C5N(C3)C(=O)N(C5%18)CN3C(=O)N(C%16C3%17)CN3C(=O)N(C%14C3%15)CN3C(=O)N(C%12C3%13)CN3C(=O)N(C%10C3%11)CN3C(=O)N(C8C39)CN3C(=O)N1C6C37)=O)=O)=O)=O)=O)=O)=O)C42>O>[NH:3]1[CH2:4][CH2:5][NH:6][CH2:7][CH2:8][NH:9][CH2:10][CH2:11][NH:12][CH2:1][CH2:2]1

参加物

4

反応物 2

HCID 11652630Cyclen tetrahydrochlorideHCID 16133299Cucurbit[8]uril

生成物 1

HCID 649631,4,7,10-Tetraazacyclododecane

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

120.0 mg of cyclen tetrahydrochloride (1,4,7,10-tetraazacyclodecane tetrahydrochloride) and 100.0 mg of cucurbit[8]uril were dissolved in water. Heating followed by slow cooling of the solution produced an inclusion complex in which a cyclen molecule was encapsulated in the cavity of cucurbit[8]uril as a colorless crystalline material.

後処理

  1. temperatureHeating
  2. temperatureby slow cooling of the solution

出典と根拠

ORDレコード
ord-b6b8935b53c644f8ac3ea17e26985234
出典データセット
uspto-grants-2007_01
特許番号
US07160466B2

反応ノート

読み込み中…