1-Pentanol → Amyl oleate

HRID 13733

反応式

HRID 13733 の反応式
[C:1]([O:20][CH2:21][CH3:22])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH2:23](O)[CH2:24][CH2:25]CC>CCOCC>[C:1]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

参加物

4

反応物 2

HCID 62761-PentanolHCID 5363269Ethyl Oleate

生成物 1

HCID 5354230Amyl oleate収率 91%

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

A mixture containing Catalyst A or B (0.05 g) and ethyl oleate (1.55 g, 5 mmol) and pentanol (10 ml) was refluxed with stirring for 40 h. On cooling ether (30 ml) was added and the catalyst was filtered off. The organic washings were combined and concentrated to give pentyl oleate as an oil (1.6 g, 91% yield).

後処理

  1. temperaturewas refluxed
  2. additionwas added
  3. filtrationthe catalyst was filtered off
  4. concentrationconcentrated

出典と根拠

ORDレコード
ord-c891a9a360914f4b89c8c19dfb2ab01a
出典データセット
uspto-grants-2010_06
特許番号
US07728159B2

関連ノート

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