1-Butanol → n-Butylphosphorodichloridate
反応式
[CH2:1]([OH:5])[CH2:2][CH2:3][CH3:4].[O:6]=[P:7](Cl)([Cl:9])[Cl:8]>C(Cl)Cl>[P:7]([Cl:9])([Cl:8])([O:5][CH2:1][CH2:2][CH2:3][CH3:4])=[O:6]参加物
4
反応条件
- 温度
- 0 °C
実験手順
To a solution of butanol (0.98 mL, 10.0 mmol) in anhydrous CH2Cl2 (10 mL) was added dropwise POCl3 (3.0 mL, 32.0 mmol) at 0° C. After stirring at 0° C. for 1 h, the mixture was refluxed for 5 h and then followed by vacuum distillation to afford butyl dichlorophosphate.
後処理
- temperaturethe mixture was refluxed for 5 h
- distillationfollowed by vacuum distillation
出典と根拠
- ORDレコード
- ord-741ee96edd9246e7866739cadb9e39d0
- 出典データセット
- uspto-grants-2007_01
- 特許番号
- US07166744B2
反応ノート
読み込み中…