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m-Toluidine → 2,2'-Dithiobis[N-(3-methylphenyl)benzamide]
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | m-Toluidine | HCID 7934 | — |
| 反応物 | 2,2'-Dithiodibenzoyl chloride | HCID 88164 | — |
| 溶媒 | Pyridine | HCID 1049 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 2,2'-Dithiobis[N-(3-methylphenyl)benzamide] | HCID 465326 | 42% |
反応手順
This compound was prepared according to the general method of Example 77 using 2,2'-dithiobisbenzoyl chloride (2.00 g, 5.83 mmol) in 50 mL of dichloromethane and m-toluidine (1.24 g, 11.6 mmol) in 10 mL of pyridine. The crude product was recrystallized from ethyl ether-ethyl acetate to yield 1.18 g of the title compound, mp 193°-195° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05668291 |
| 出典データセット | uspto-grants-1997_09 |
| ORD ID | ord-ab7941cd92e34f78aa46d97b146337c5 |
| 出典メモ | uspto-grants-1997_09 |