関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dimethyl Sulfoxide | HCID 679 | — |
| 反応物 | Sodium Bicarbonate | HCID 516892 | — |
| 反応物 | Hexadecenyl bromide | HCID 54030172 | — |
| 生成物 | 16-Bromohexadec-5-ene | HCID 54440187 | — |
反応手順
Hexadecenyl bromide (360 g; 1.2 mol) and 1800 mL (2660 g; 34 mol) of DMSO were mixed and heated to 60° C. for 30 minutes. Then, NaHCO3 and a co-solvent were added, pressure reduced and temperature raised for the period of time specified in Table I. Reaction mixture was then cooled and concentrated on a rotary evaporator. GLC analysis was then carried out to determine aldehyde/alcohol ratios in the reaction product. Results from reactions employing several different co-solvents are summarized in Table I as runs 5-9.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US04579977 |
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| 出典データセット | uspto-grants-1986_04 |
|---|
| ORD ID | ord-96d7a0d1a2dc4bbdacb0e62356c65943 |
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| 出典メモ | uspto-grants-1986_04 |
|---|
