4-Fluoro-3-nitrobenzotrifluoride → 2,4-Hexadiyn-1,6-diol bis-(2-nitro-4-trifluoromethylphenyl)ether

HRID 1380270

反応式

HRID 1380270 の反応式
[CH2:1]([OH:8])[C:2]#[C:3][C:4]#[C:5][CH2:6][OH:7].F[C:10]1[CH:15]=[CH:14][C:13]([C:16]([F:19])([F:18])[F:17])=[CH:12][C:11]=1[N+:20]([O-:22])=[O:21]>>[CH2:1]([OH:8])[C:2]#[C:3][C:4]#[C:5][CH2:6][OH:7].[N+:20]([C:11]1[CH:12]=[C:13]([C:16]([F:19])([F:18])[F:17])[CH:14]=[CH:15][C:10]=1[O:8][C:1]1[CH:6]=[CH:5][C:4]([C:16]([F:19])([F:18])[F:17])=[CH:3][C:2]=1[N+:20]([O-:22])=[O:21])([O-:22])=[O:21]

参加物

3

反応物 2

HCID 677784-Fluoro-3-nitrobenzotrifluorideHCID 94973Diacetylene glycol

生成物 1

HCID 886877102,4-Hexadiyn-1,6-diol bis-(2-nitro-4-trifluoromethylphenyl)ether

実験手順

Reaction of 2,4-hexadiyne-1,6-diol (1 g) with 4-fluoro-3-nitro-benzotrifluoride (4 g.) following the procedure of Example 3 yielded the desired product. Recrystallization from ethanol gave pale yellow needles. (1.1 g., 25%) m.p. 137° C. I.R. (KBr): 1620(NO2), 1120 682 (CF3)cm-1.

出典と根拠

ORDレコード
ord-3c586a1186c748db81cc0bdcf05a56e3
出典データセット
uspto-grants-1986_04
特許番号
US04581315

関連ノート

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