Chlorine → 1-Chloro-4-(trifluoromethoxy)benzene

HRID 1380715

反応式

HRID 1380715 の反応式
[Cl:1]Cl.[N+]([C:6]1[CH:11]=[CH:10][C:9]([O:12][C:13]([F:16])([F:15])[F:14])=[CH:8][CH:7]=1)([O-])=O>>[Cl:1][C:6]1[CH:11]=[CH:10][C:9]([O:12][C:13]([F:16])([F:15])[F:14])=[CH:8][CH:7]=1

参加物

3

反応物 2

HCID 24526Chlorine2 回HCID 5224051-Nitro-4-(trifluoromethoxy)benzene

生成物 1

HCID 27772731-Chloro-4-(trifluoromethoxy)benzene収率 83%

実験手順

Chlorine and p-nitrotrifluoromethoxybenzene (10.7 parts) were fed simultaneously at a molar ratio of 3:1, Cl2 :organic reactant, into a vapor phase reactor maintained at 300° to 320° C. over a 30 minute period to yield 8.2 parts of p-chlorotrifluoromethoxybenzene (83% yield). The structure of the product was confirmed by gas chromatographic-mass spectrum and F19 nuclear magnetic resonance analysis.

後処理

  1. temperatureorganic reactant, into a vapor phase reactor maintained at 300° to 320° C. over a 30 minute period

出典と根拠

ORDレコード
ord-4b28e585bc67489cb3e1fb911d51625c
出典データセット
uspto-grants-1986_04
特許番号
US04582948

関連ノート

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