Phosphoric Acid → 6-Deoxy-6-(formylamino)-L-sorbose

HRID 1382490ノート

反応式

HRID 1382490 の反応式
P(=O)(O)(O)O.[CH:6]([NH:8][CH:9]([C@@H:11]([C@H:13]([C@@H:15]([C@@H:17]([CH2:19][OH:20])[OH:18])[OH:16])[OH:14])[OH:12])O)=[O:7]>O>[CH:6]([NH:8][CH2:9][C@H:11]([OH:12])[C@@H:13]([OH:14])[C@H:15]([OH:16])[C:17](=[O:18])[CH2:19][OH:20])=[O:7]

参加物

4

反応物 2

HCID 1004Phosphoric AcidHCID 131715863HCID 131715863、化合物2 回

生成物 1

HCID 228415056-Deoxy-6-(formylamino)-L-sorbose

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

To a suspension of 40 g of Gluconobacter oxidans spp. suboxidans (DSM 50049) in 1 l of tap water, brought to pH 4.5 with phosphoric acid, are added at 32° C. and 700 rpm with venting of 3 l of air/hour 200 g of N-formylaminosorbitol, followed 4 hours later by a further 200 g of N-formylaminosorbitol. After 22 hours the reaction has ended, the cells are centrifuged off and discarded. The product is isolated as an oil by concentrating in vacuo.

後処理

  1. additionare added at 32° C.
  2. customThe product is isolated as an oil
  3. concentrationby concentrating in vacuo

出典と根拠

ORDレコード
ord-492164ec61bd40329d8a7b27a129fa0f
出典データセット
uspto-grants-1989_02
特許番号
US04806650

反応ノート

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