Veratrole → HCID 11087524、化合物

HRID 1383299

反応式

HRID 1383299 の反応式
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[O:9][CH3:10].[Cl-].[Cl-].[Cl-].[Al+3].[C:15]1(=[O:25])[O:20][C:18](=[O:19])[C@H:17]2[CH2:21][CH:22]=[CH:23][CH2:24][C@@H:16]12>ClCCl>[CH3:1][O:2][C:3]1[CH:8]=[C:7]([CH:6]=[CH:5][C:4]=1[O:9][CH3:10])[C:15]([C@H:16]1[CH2:24][CH:23]=[CH:22][CH2:21][C@H:17]1[C:18]([OH:20])=[O:19])=[O:25]

参加物

5

反応物 3

HCID 7043VeratroleHCID 98495Tetrahydrophthalic anhydride, cis-HCID 6451240Aluminum(III) Chloride

生成物 1

HCID 11087524HCID 11087524、化合物

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

0.5 mole of 1,2-dimethoxybenzene was added slowly to a suspension of 0.5 mole aluminiumtrichloride in 1 l of dichloromethane at 0° C. After complete addition, cis-1,2,3,6-tetrahydrophthalic acid anhydride was added to the solution. After 8 hours of reflux the solution was poured onto ice. The organic layer was dried over magnesium sulfate and evaporated. The residue was washed with diethyl ether and dried. M.p. 110-112° C.

後処理

  1. additionwas added to the solution
  2. temperatureAfter 8 hours of reflux the solution
  3. additionwas poured onto ice
  4. dry with materialThe organic layer was dried over magnesium sulfate
  5. customevaporated
  6. washThe residue was washed with diethyl ether
  7. customdried

出典と根拠

ORDレコード
ord-374b144bb16f4fd39577162cc8f03fcb
出典データセット
uspto-grants-2001_07
特許番号
US06255303B1

関連ノート

読み込み中…