1-Bromohexane → HCID 11732181、化合物

HRID 1383705ノート

反応式

HRID 1383705 の反応式
[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

参加物

3

反応物 2

HCID 81011-BromohexaneHCID 2519872,7-Dichlorofluorene

生成物 1

HCID 11732181HCID 11732181、化合物収率 91%

実験手順

2,7-Dichloro-9,9-di(1-hexyl)fluorene was prepared from 2,7-dichlorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield; melting point 66° C. to 67° C. HPLC analysis showed that the sample was 99 percent or greater pure and the spectral data confirmed the title structure.

後処理

  1. customas colorless crystals (recrystallized from hexane) in 91 percent yield

出典と根拠

ORDレコード
ord-792813a0ffbe49b8af04afd122974de5
出典データセット
uspto-grants-2001_07
特許番号
US06255447B1

反応ノート

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