関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Phosphorus pentachloride | HCID 24819 | — |
| 反応物 | Dibenzyl 3,4,5-trimethoxyphenylphosphonate | HCID 54545930 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | Benzyl 3,4,5-trimethoxyphenylphosphonochloridate | HCID 21185535 | — |
反応手順
Phosphorous pentachloride (1.15 mmol) is added to a mixture of diester 2 (1 mmol) in 5 mL of CHCl3. The mixture is heated at 60° C. until 1H NMR of an aliquot shows that no starting material remains (approximately 4 hours). The mixture is cooled to room temperature, and the volatile components are removed in vacuo overnight
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06258360B1 |
|---|
| 出典データセット | uspto-grants-2001_07 |
|---|
| ORD ID | ord-951b36517c3041079e84d5fcd56e65b5 |
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| 出典メモ | uspto-grants-2001_07 |
|---|
