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1,1,1,3,3,3-Hexafluoro-2-propanol → Tri-tert-butylphosphonium Tetraphenylborate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,1,1,3,3,3-Hexafluoro-2-propanol | HCID 13529 | — |
| 反応物 | Tris(1,1-dimethylethyl)phosphine | HCID 83681 | — |
| 反応物 | Sodium Tetraphenylborate | HCID 2723787 | — |
| 生成物 | Tri-tert-butylphosphonium Tetraphenylborate | HCID 23136663 | 77% |
反応手順
Tri-tert-butylphosphine is reacted with 1,1,1,3,3,3-hexafluoro-2-propanol and with sodium tetraphenylborate to produce tri-tert-butylphosphonium tetraphenylborate (77% yield). A similar process is described in which tricyclohexylphosphine is used as starting material to produce tricyclohexylphosphonium tetraphenylborate (77% yield) (see Nonpatent Document 7).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07728176B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-32062efb59614351b3cd53ae313ef854 |
| 出典メモ | uspto-grants-2010_06 |