Tert-Butylamine → 1-(bromomethyl)-N-(1,1-dimethylethyl)-1,1-dimethylsilanamine
反応式
[Br:1][CH2:2][Si:3](Cl)([CH3:5])[CH3:4].[C:7]([NH2:11])([CH3:10])([CH3:9])[CH3:8]>CCOCC>[Br:1][CH2:2][Si:3]([CH3:5])([CH3:4])[NH:11][C:7]([CH3:10])([CH3:9])[CH3:8]参加物
4
実験手順
To a stirred solution of 10.00 g (53.32 mmol) of (bromomethyl)chlorodimethylsilane in 200 ml, of diethylether a solution of 7.80 g (106.64 mmol) of t-butyl amine in 10 mL of ether was added. A white solid deposited instantaneously. The reaction mixture was stirred overnight, filtered through a medium frit and the solvent was removed under reduced pressure to give 11.06 g of colorless liquid. Yield 93 percent.
後処理
- filtrationfiltered through a medium frit
- customthe solvent was removed under reduced pressure
出典と根拠
- ORDレコード
- ord-affda961a3a0478f98223a0d82b9e140
- 出典データセット
- uspto-grants-2001_07
- 特許番号
- US06268444B1
反応ノート
読み込み中…