Water → Bis(diphenylmethyl) ether

HRID 1388240ノート

反応式

HRID 1388240 の反応式
Cl[CH:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[OH2:15]>>[CH:2]([O:15][CH:2]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

3

反応物 2

HCID 962Water2 回HCID 7035Chlorodiphenylmethane

生成物 1

HCID 11323Bis(diphenylmethyl) ether

実験手順

A mixture of 37 g of chlorodiphenylmethane and 100 ml of water were refluxed under nitrogen for 16 hours. After cooling the water was decanted and 40 ml of ethanol was added to induce crystallization. The yellow solid was recrystallized 3 times from ethanol to give 21.9 g of dibenzhydryl ether, m.p. 108°-110°.

後処理

  1. temperaturewere refluxed under nitrogen for 16 hours
  2. customwas decanted
  3. addition40 ml of ethanol was added
  4. customcrystallization
  5. customThe yellow solid was recrystallized 3 times from ethanol

出典と根拠

ORDレコード
ord-de8082e424634f9590c5c2ee70d0ae06
出典データセット
uspto-grants-1984_02
特許番号
US04431497

反応ノート

読み込み中…