関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Ethanol | HCID 702 | — |
| 反応物 | Diisobutyl aluminium chloride | HCID 16686353 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | Chloro-ethoxy-isobutyl-aluminum | HCID 20469170 | — |
反応手順
A solution of 23.75 g (0.516 mol) of absolute ethanol in 350 ml of absolute toluene is added dropwise during 1 hour to a solution of 91.1 g (0.516 mol) of diisobutylaluminum chloride in 350 ml of absolute toluene at 0° C. and under a protective gas atmosphere (argon). Thereafter, the mixture is warmed at 50° C. for 1 hour and cooled to 5° C., to yield the chloro-ethoxy-isobutyl-aluminum starting material.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04434178 |
|---|
| 出典データセット | uspto-grants-1984_02 |
|---|
| ORD ID | ord-c8ad5093cd0d48f5a3d2cf671473dfae |
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| 出典メモ | uspto-grants-1984_02 |
|---|
