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Benzene → 4-Vinylpyridine styrene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzene | HCID 241 | — |
| 反応物 | Azobisisobutyronitrile | HCID 6547 | — |
| 反応物 | Styrene | HCID 7501 | — |
| 反応物 | 2-Vinylpyridine | HCID 7521 | — |
| 溶媒 | Hexane | HCID 8058 | — |
| 生成物 | 4-Vinylpyridine styrene | HCID 12666455 | 20% |
反応手順
In a 200 ml three necked flask were charged 21 g of 4-vinylpyridine, 21 g of styrene and 0.1 g of azobisisobutyronitrile and 90 ml of benzene. The mixture was polymerized at 80° C. for 6 hrs under a nitrogen atmosphere. The reaction liquid was poured into a large amount of n-hexane to thereby obtain white precipitates. After filtering and drying, a white powder was obtained. The molar fraction of vinylpyridine in the polymer was 0.57 and the yield was 20%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04245027 |
| 出典データセット | uspto-grants-1981_01 |
| ORD ID | ord-2fc78f28946d42f0a1e6089859ad9551 |
| 出典メモ | uspto-grants-1981_01 |