Benzene → (3-Ethyl-2-hydroxyphenyl)(phenyl)methanone

HRID 1391334ノート

反応式

HRID 1391334 の反応式
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH:7][C:8]1[C:16]([CH2:17][CH3:18])=[CH:15][CH:14]=[CH:13][C:9]=1[C:10](Cl)=[O:11]>>[OH:7][C:8]1[C:16]([CH2:17][CH3:18])=[CH:15][CH:14]=[CH:13][C:9]=1[C:10]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)=[O:11]

参加物

3

反応物 2

HCID 241BenzeneHCID 450815813-Ethyl-2-hydroxybenzoyl chloride

生成物 1

HCID 12562658(3-Ethyl-2-hydroxyphenyl)(phenyl)methanone収率 58.1%

実験手順

This compound (44.67 g) was prepared from benzene (172 g, 2.2 mole) and 2-hydroxy-3-ethyl benzoic acid chloride (63.15 g, 0.34 mole), using the same conditions as in Example 4. The b.p. of the compound was 123°-126° C./0.14 mm, ηD22 1.6081, γ max. (film) 1630 cm-1. The same compound was obtained using the method of Example 2.

後処理

  1. customwas 123°-126° C.
  2. customThe same compound was obtained

出典と根拠

ORDレコード
ord-3c7f3bb54ed14dc398560c8d86240b1e
出典データセット
uspto-grants-1979_02
特許番号
US04141995

反応ノート

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