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Mesitylene → (1R*,4S*)-6-allyl-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-ol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Mesitylene | HCID 7947 | — |
| 反応物 | (1R*,4S*)-5-(allyloxy)-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalene | HCID 68584256 | — |
| 生成物 | (1R*,4S*)-6-allyl-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-ol | HCID 68583880 | 80% |
反応手順
Treatment of (1R*,4S*)-5-(allyloxy)-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalene (15.8 g, 0.069 mol) in refluxing mesitylene generally according to the procedure described for Intermediate 1 gave 12.58 g (80%) of (1R*,4S*)-6-allyl-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-ol as a colorless oil. Anal. calcd. for C20H22O.0.2H2O: C, 77.02; H, 7.93. Found: C, 76.68; H, 7.88.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07728155B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-b13fc06abfcf40eb8c81fec33e28e61c |
| 出典メモ | uspto-grants-2010_06 |