化工社化工社 化学情報印刷レポート · 研究参考用
Mesitylene → 5-Allyl-6-chloroindan-4-ol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Mesitylene | HCID 7947 | — |
| 反応物 | 4-(Allyloxy)-6-chloroindane | HCID 68583970 | — |
| 生成物 | 5-Allyl-6-chloroindan-4-ol | HCID 68585868 | 56% |
反応手順
Treatment of 4-(allyloxy)-6-chloroindane (8.0 g, 0.038 mol) in refluxing mesitylene (270 mL) generally according to the procedure described for Intermediate 1 afforded 4.5 g (56%) of 5-allyl-6-chloroindan-4-ol as a colorless oil which solidified into a white solid upon standing. mp 37-39° C.; Anal. calcd. for C12H13ClO.0.1H2O: C, 68.48; H, 6.32. Found: C, 68.54; H, 6.29.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07728155B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-a22c5adcc1c84f2c827b68d9447ff539 |
| 出典メモ | uspto-grants-2010_06 |