化工社化工社 化学情報印刷レポート · 研究参考用
3,5,7,3',4'-Pentahydroxyflavanone → Vanillin
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3,5,7,3',4'-Pentahydroxyflavanone | HCID 471 | — |
| 反応物 | Vanillin | HCID 1183 | — |
| 反応物 | Dimethylaminocinnamaldehyde | HCID 54119736 | — |
| 溶媒 | Hydrochloric Acid | HCID 313 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Vanillin | HCID 1183 | 1% |
| 生成物 | 2-(3,4-dihydroxyphenyl)-3,4-dihydro-2H-1-benzopyran-3,5,7-triol | HCID 1203 | — |
| 生成物 | Dimethylaminocinnamaldehyde | HCID 54119736 | — |
反応手順
Working solution of 1% vanillin was prepared by dissolving 0.1 g of vanillin in 10 mL of 5 N HCl, whereas 5% dimethylaminocinnamaldehyde (DMACA) was prepared in methanol containing 5% H2SO4. Lyophilized extract for 100 mg of dry kernels was dissolved in 0.5 mL of vanillin or DMACA working solutions. Taxifolin and catechin each at a concentration of 100 ppm were used as reference compounds for color reactions. Because vanillin is catechin-specific and produces bright red color, no color is developed when it reacts with taxifolin. DMACA reacting with catechin produces dark greenish blue color, whereas reacting with taxifolin produces purple color.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07348475B2 |
| 出典データセット | uspto-grants-2008_03 |
| ORD ID | ord-1f667d9385214a6a8ee33448a7929562 |
| 出典メモ | uspto-grants-2008_03 |