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HRID 1394571作成日:2026年10月27日

3,5,7,3',4'-Pentahydroxyflavanone → Vanillin

https://huagongshe.com/reaction/1394571

反応式

関与物質

役割名称HCID仕込み量
反応物3,5,7,3',4'-PentahydroxyflavanoneHCID 471—
反応物VanillinHCID 1183—
反応物DimethylaminocinnamaldehydeHCID 54119736—
溶媒Hydrochloric AcidHCID 313—
溶媒MethanolHCID 887—
生成物VanillinHCID 11831%
生成物2-(3,4-dihydroxyphenyl)-3,4-dihydro-2H-1-benzopyran-3,5,7-triolHCID 1203—
生成物DimethylaminocinnamaldehydeHCID 54119736—

反応手順

Working solution of 1% vanillin was prepared by dissolving 0.1 g of vanillin in 10 mL of 5 N HCl, whereas 5% dimethylaminocinnamaldehyde (DMACA) was prepared in methanol containing 5% H2SO4. Lyophilized extract for 100 mg of dry kernels was dissolved in 0.5 mL of vanillin or DMACA working solutions. Taxifolin and catechin each at a concentration of 100 ppm were used as reference compounds for color reactions. Because vanillin is catechin-specific and produces bright red color, no color is developed when it reacts with taxifolin. DMACA reacting with catechin produces dark greenish blue color, whereas reacting with taxifolin produces purple color.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US07348475B2
出典データセットuspto-grants-2008_03
ORD IDord-1f667d9385214a6a8ee33448a7929562
出典メモuspto-grants-2008_03