HCID 135428345、化合物 → 1,4-Bis(alpha-aminobenzyl)benzene

HRID 1395253ノート

反応式

HRID 1395253 の反応式
[C:1](=[N:23]O)([C:8]1[CH:13]=[CH:12][C:11]([C:14](=[N:21]O)[C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[H][H]>C(O)C.N.[Ni]>[NH2:21][CH:14]([C:11]1[CH:12]=[CH:13][C:8]([CH:1]([NH2:23])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)=[CH:9][CH:10]=1)[C:15]1[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

参加物

6

反応物 2

HCID 135428345HCID 135428345、化合物HCID 178418361HCID 178418361、化合物

生成物 1

HCID 203406881,4-Bis(alpha-aminobenzyl)benzene

試薬・触媒・溶媒 3

HCID 935Nickel触媒HCID 222Ammonia溶媒HCID 702Ethanol溶媒

実験手順

The dioxime from Step 2 (30 g) is dissolved in ethyl alcohol (300 ml), saturated with ammonia gas and Raney nickel catalyst W-6 (2 g) added. The mixture is subjected to 700 psi hydrogen pressure and heated at 70° for three hours. The catalyst is removed by filtration and 220 ml of ethanol is removed by distillation. The pale yellow precipitate is filtered and dried.

後処理

  1. addition(2 g) added
  2. temperatureheated at 70° for three hours
  3. customThe catalyst is removed by filtration and 220 ml of ethanol
  4. customis removed by distillation
  5. filtrationThe pale yellow precipitate is filtered
  6. customdried

出典と根拠

ORDレコード
ord-9d13d61ba8d44ee299af2f117325c21f
出典データセット
uspto-grants-1980_05
特許番号
US04202904

反応ノート

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