Sodium Methoxide → HCID 178493296、化合物

HRID 1395554

反応式

HRID 1395554 の反応式
[CH:1]([N:4]([CH:18]([CH3:20])[CH3:19])[CH2:5][CH2:6][NH:7][C:8]1[CH:13]=[C:12]([N+]([O-])=O)[CH:11]=[CH:10][N+:9]=1[O-:17])([CH3:3])[CH3:2].[CH3:21][O-:22].[Na+]>CO>[CH:1]([N:4]([CH:18]([CH3:20])[CH3:19])[CH2:5][CH2:6][NH:7][C:8]1[CH:13]=[C:12]([O:22][CH3:21])[CH:11]=[CH:10][N+:9]=1[O-:17])([CH3:3])[CH3:2]

参加物

4

反応物 2

HCID 10942334Sodium MethoxideHCID 178457399HCID 178457399、化合物

生成物 1

HCID 178493296HCID 178493296、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

2-(2-Diisopropylaminoethylamino)-4-nitropyridine-N-oxide (10.0 g., 35.5 mmole) is added to a solution of sodium methoxide (3.0 g., 55 mmole) in dry methanol (100 ml.) and refluxed for 4 hours. The solvent is evaporated and the residue dissolved in chloroform, washed with water, dried over sodium sulfate and evaporated to give oily product.

後処理

  1. temperaturerefluxed for 4 hours
  2. customThe solvent is evaporated
  3. dissolutionthe residue dissolved in chloroform
  4. washwashed with water
  5. dry with materialdried over sodium sulfate
  6. customevaporated
  7. customto give oily product

出典と根拠

ORDレコード
ord-36d8a0ae002e49b9beada766ba3a8b0e
出典データセット
uspto-grants-1980_05
特許番号
US04203988

関連ノート

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