3-[4-(Methylsulfanyl)phenyl]-1-phenylpropan-1-one → HCID 131732161、化合物

反応式

CSC1C=CC(CCC(C2C=CC=CC=2)=O)=CC=1.[CH3:19][S:20][C:21]1[CH:26]=[CH:25][C:24]([CH2:27][CH2:28]/[C:29](/[C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=2)=[CH:30]/[C:31]([O:33][CH2:34][CH3:35])=[O:32])=[CH:23][CH:22]=1>>[CH3:19][S:20][C:21]1[CH:22]=[CH:23][C:24]([CH2:27][CH2:28]/[C:29](/[C:36]2[CH:37]=[CH:38][CH:39]=[CH:40][CH:41]=2)=[CH:30]\[C:31]([O:33][CH2:34][CH3:35])=[O:32])=[CH:25][CH:26]=1

参加物

反応物 2

HCID 247259643-[4-(Methylsulfanyl)phenyl]-1-phenylpropan-1-one

HCID 131732162HCID 131732162、化合物

生成物 1

HCID 131732161HCID 131732161、化合物

実験手順

By a procedure similar to that of example 1.85.3, starting from 3-[4-(methylthio)phenyl]-1-phenylpropan-1-one, (Z)-ethyl 5-[4-(methylthio)phenyl]-3-phenylpent-2-enoate and (E)-ethyl 5-[4-(methylthio)phenyl]-3-phenylpent-2-enoate were obtained as colourless oils.

出典と根拠

ORDレコード: ord-3dade121cc4b4b9fa4efddf43ee2356a
出典データセット: uspto-grants-2014_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08912186B2

反応ノート

読み込み中…