Hydroxylamine → 4-(4-Bromo-2-chloro-phenoxy)-benzaldehyde-oxime

HRID 1406359ノート

反応式

HRID 1406359 の反応式
[Br:1][C:2]1[CH:16]=[CH:15][C:5]([O:6][C:7]2[CH:14]=[CH:13][C:10]([CH:11]=O)=[CH:9][CH:8]=2)=[C:4]([Cl:17])[CH:3]=1.[NH2:18][OH:19]>CN(C=O)C>[Br:1][C:2]1[CH:16]=[CH:15][C:5]([O:6][C:7]2[CH:14]=[CH:13][C:10]([CH:11]=[N:18][OH:19])=[CH:9][CH:8]=2)=[C:4]([Cl:17])[CH:3]=1

参加物

4

反応物 2

HCID 787HydroxylamineHCID 288931534-(4-Bromo-2-chloro-phenoxy)-benzaldehyde

生成物 1

HCID 866588184-(4-Bromo-2-chloro-phenoxy)-benzaldehyde-oxime

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

20 mg (0.06 mmol) of 4-(4-bromo-2-chloro-phenoxy)-benzaldehyde were stirred with 20 μL (0.33 mmol) of hydroxylamine solution (50% in water) in 2 mL f DMF at 80° C. for 1 h. The reaction mixture was purified by chromatography (reversed phase).

後処理

  1. customThe reaction mixture was purified by chromatography (reversed phase)

出典と根拠

ORDレコード
ord-64fa39e5ed964d61b5f7065c943dcdbc
出典データセット
uspto-grants-2014_12
特許番号
US08916589B2

反応ノート

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