化工社化工社 化学情報印刷レポート · 研究参考用
Ammonia → Tatb
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | Pentanitroaniline | HCID 11023554 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Tatb | HCID 18286 | — |
反応手順
According to this invention, the 4-nitro group or trinitrotoluene (TNT) is selectively reduced by H2S in p-dioxane to produce 4-amino-2,6-dinitrotoluene. This latter compound is then nitrated with HNO3 in H2SO4 to produce pentanitroaniline. Finally the pentanitroaniline is reacted with NH3 in benzene, methylene chloride or another suitable solvent to produce a quantitative yield of TATB. The method of this invention is easily carried out and all reactants are inexpensive.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04248798 |
| 出典データセット | uspto-grants-1981_02 |
| ORD ID | ord-c283ec2468c44de395a48e3784755499 |
| 出典メモ | uspto-grants-1981_02 |