Methyl carbazate → HCID 136388419、化合物

HRID 1413304ノート

反応式

HRID 1413304 の反応式
[CH3:1][C:2]1[NH:6][C:5]([C:7]2[CH:8]=[C:9]([CH3:13])[CH:10]=[CH:11][CH:12]=2)=[N:4][C:3]=1[CH:14]=O.[C:16]([O:20][CH3:21])(=[O:19])[NH:17][NH2:18]>C(O)(=O)C.C(Cl)Cl>[CH3:1][C:2]1[NH:6][C:5]([C:7]2[CH:8]=[C:9]([CH3:13])[CH:10]=[CH:11][CH:12]=2)=[N:4][C:3]=1[CH:14]=[N:18][NH:17][C:16]([O:20][CH3:21])=[O:19]

参加物

5

反応物 2

HCID 80519Methyl carbazateHCID 224119984-Methyl-2-(3-methylphenyl)-1H-imidazole-5-carboxaldehyde

生成物 1

HCID 136388419HCID 136388419、化合物

試薬・触媒・溶媒 2

HCID 176Acetic Acid触媒HCID 6344Dichloromethane溶媒

実験手順

A mixture of 5-methyl-2-m-tolyl-4-imidazolecarboxaldehyde (6.9 l g, 0.034 mole), methyl carbazate (3.1 g, 0.034 mole). methylene chloride (70 ml) and acetic acid (1 drop) is refluxed for 1 hour. The precipitated white solid is collected by filtration to yield 7.1 g (0.026 mole), mp. 162°-164° C.

後処理

  1. filtrationThe precipitated white solid is collected by filtration
  2. customto yield 7.1 g (0.026 mole), mp. 162°-164° C.

出典と根拠

ORDレコード
ord-2861b5892a684987881acb9619fd7d84
出典データセット
uspto-grants-1981_02
特許番号
USRE030511

反応ノート

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