化工社化工社 化学情報印刷レポート · 研究参考用
9,10-Anthracenedione, 2-amino-3-chloro- → Anthrimide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 9,10-Anthracenedione, 2-amino-3-chloro- | HCID 6771 | — |
| 反応物 | Nitrobenzene | HCID 7416 | — |
| 反応物 | Sodium Carbonate | HCID 10340 | — |
| 反応物 | 1-Amino-4-chloro-9,10-anthracenedione | HCID 17884 | — |
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 生成物 | Anthrimide | HCID 6700 | — |
反応手順
21 g of 6-chloro-2-(4-diphenyl)-anthrapyrimidine (obtained by reacting 1-amino-4-chloroanthraquinone with diphenyl-4-carboxylic acid N-methylamide in the presence of thionyl chloride (in accordance with D.R.P. 566,474)) are condensed, in accordance with Example 1, in 250 parts of nitrobenzene in the presence of 7.5 parts of sodium carbonate and 0.25 part of copper-1 chloride with 13.5 parts of 1-amino-3-chloroanthraquinone. 28 parts are obtained of the anthrimide of the formula ##SPC9##
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04001170 |
| 出典データセット | uspto-grants-1977_01 |
| ORD ID | ord-9382bbe1a6aa4dd395b41c896390f9e5 |
| 出典メモ | uspto-grants-1977_01 |