2-Methoxy-4-(2-nitroethenyl)-1-(phenylmethoxy)benzene → Phenethylamine, 4-(benzyloxy)-3-methoxy-

反応式

[CH2:1]([O:8][C:9]1[CH:19]=[CH:18][C:12]([CH:13]=[CH:14][N+:15]([O-])=O)=[CH:11][C:10]=1[O:20][CH3:21])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(OC1C=C(C=CC=1OC)C=C[N+]([O-])=O)C1C=CC=CC=1>>[CH2:1]([O:8][C:9]1[CH:19]=[CH:18][C:12]([CH2:13][CH2:14][NH2:15])=[CH:11][C:10]=1[O:20][CH3:21])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

反応物 2

HCID 158282-Methoxy-4-(2-nitroethenyl)-1-(phenylmethoxy)benzene

HCID 2332022-Benzyloxy-1-methoxy-4-(2-nitrovinyl)benzene

生成物 1

HCID 200382Phenethylamine, 4-(benzyloxy)-3-methoxy-

実験手順

Substitution of a like quantity of 4-benzyloxy-3-methoxy-β-nitrostyrene for the 3-benzyloxy-4-methoxy-β-nitrostyrene used above and substantial repetition of the foregoing procedure affords, as an oil, 4-benzyloxy-3-methoxy phenethylamine.

出典と根拠

ORDレコード: ord-7e60360e083e46018ceb940356984101
出典データセット: uspto-grants-1977_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04001244

反応ノート

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