1-Nitro-4-(3-phenylpropoxy)benzene → Aniline, p-(3-phenylpropoxy)-

HRID 1415348ノート

反応式

HRID 1415348 の反応式
[C:1]1([CH2:7][CH2:8][CH2:9][O:10][C:11]2[CH:16]=[CH:15][C:14]([N+:17]([O-])=O)=[CH:13][CH:12]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>CO.[Ni].[H][H]>[C:1]1([CH2:7][CH2:8][CH2:9][O:10][C:11]2[CH:12]=[CH:13][C:14]([NH2:17])=[CH:15][CH:16]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

参加物

5

反応物 1

HCID 214818451-Nitro-4-(3-phenylpropoxy)benzene

生成物 1

HCID 42154Aniline, p-(3-phenylpropoxy)-

試薬・触媒・溶媒 3

HCID 935Nickel触媒HCID 887Methanol溶媒HCID 178418361HCID 178418361、化合物溶媒

実験手順

99 g of 4-(3'-phenyl-propoxy)-nitrobenzene is dissolved in 2000 ml of methanol and hydrogenated with Raney nickel until the absorption of hydrogen is completed. The catalyst is filtered off and the filtrate is concentrated by evaporation to obtain, as a crystalline residue, 4-(3'-phenylpropoxy)-aniline having a melting point of 55°- 57°. -

後処理

  1. filtrationThe catalyst is filtered off
  2. concentrationthe filtrate is concentrated by evaporation

出典と根拠

ORDレコード
ord-b76eb5365a4e442faeb86e2e4339cc8a
出典データセット
uspto-grants-1977_01
特許番号
US04004907

反応ノート

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