4-Methoxybenzaldehyde → 4-(4-Methoxyphenyl)but-3-en-2-one

HRID 1415466

反応式

HRID 1415466 の反応式
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([CH:9]=O)=[CH:7][CH:8]=1>[O-2].[Zn+2].CC(C)=O>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([CH:9]=[CH:8][C:3](=[O:2])[CH3:4])=[CH:5][CH:4]=1

参加物

4

反応物 1

HCID 312444-Methoxybenzaldehyde

生成物 1

HCID 954144-(4-Methoxyphenyl)but-3-en-2-one収率 90%

試薬・触媒・溶媒 2

HCID 3007857Zinc Oxide触媒HCID 180Acetone溶媒

実験手順

50 Parts of anisaldehyde, 100 parts of acetone and 15 parts of zinc oxide are heated for half an hour at 200° C and a pressure of 60 atmospheres. 46.2 parts of 4-(p-methoxyphenyl)-3-buten-2-one is obtained analogously to Example 9 in the form of yellowish crystals having a melting point of 74° C and a boiling point of 109° to 110° C at 0.1 mm. The yield is 90% of theory (based on anisaldehyde) at a conversion of 79% of theory.

出典と根拠

ORDレコード
ord-16da43dc0d9243d98df5c95573eb1792
出典データセット
uspto-grants-1977_01
特許番号
US04005147

関連ノート

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