化工社化工社 化学情報印刷レポート · 研究参考用
Hydrochloric Acid → Di(tetrachlorophenyl)tetrachlorocyclopentadiene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Hexachlorocyclopentadiene | HCID 6478 | — |
| 反応物 | 1,2,3,4-Tetrachlorobenzene | HCID 12463 | — |
| 反応物 | Aluminum(III) Chloride | HCID 6451240 | — |
| 生成物 | Di(tetrachlorophenyl)tetrachlorocyclopentadiene | HCID 54039303 | — |
反応手順
A mixture of 1,2,3,4-tetrachlorobenzene, 130 grams (0.6 mole), hexachlorocyclopentadiene, 65 grams (0.24 mole), and aluminum chloride, 5 grams, was heated on a steam bath at 75°-90° centigrade until the evolution of hydrogen chloride stopped and the reaction mixture solidified. The purple solid was triturated with acetone to dissolve the aluminum chloride, filtered, washed with acetone and dried to give a tan, solid product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04005153 |
| 出典データセット | uspto-grants-1977_01 |
| ORD ID | ord-b9208cc0342340e587b3093fb7374cf0 |
| 出典メモ | uspto-grants-1977_01 |