Taurine → Magnesium taurate

HRID 1417129ノート

反応式

HRID 1417129 の反応式
[OH-].[Mg+2:2].[OH-].[NH2:4][CH2:5][CH2:6][S:7]([OH:10])(=[O:9])=[O:8]>O.CO>[CH2:5]([NH2:4])[CH2:6][S:7]([O-:10])(=[O:9])=[O:8].[CH2:5]([NH2:4])[CH2:6][S:7]([O-:10])(=[O:9])=[O:8].[Mg+2:2]

参加物

5

反応物 2

HCID 1123TaurineHCID 73981Magnesium Hydroxide

生成物 1

HCID 13343447Magnesium taurate

試薬・触媒・溶媒 2

HCID 887Methanol溶媒HCID 962Water溶媒

実験手順

A mixture of magnesium hydroxide (433 mg, 7.46 mmol; Aldrich) and taurine (1.87 g, 14.9 mmol) in 20 ml water was heated under reflux for seven hours. The resulting milky mixture was allowed to cool, diluted with 40 ml methanol and allowed to stand overnight at room temperature. A white powder, consisting mostly of magnesium taurate complex, was removed by filtration. The clear filtrate was concentrated under vacuum to a pasty slurry, then diluted slowly with 10 ml methanol. After 2 hours, crystalline magnesium taurate salt was obtained by filtration. The yield was 940 mg (41%). The melting point (decomposition) was about 300° C. This salt was identical to that obtained in Example 2.

後処理

  1. temperaturewas heated
  2. temperatureunder reflux for seven hours
  3. temperatureto cool
  4. customwas removed by filtration
  5. concentrationThe clear filtrate was concentrated under vacuum to a pasty slurry
  6. additiondiluted slowly with 10 ml methanol
  7. waitAfter 2 hours

出典と根拠

ORDレコード
ord-07f0f90de0f44fda9e2f4f2117374e0a
出典データセット
uspto-grants-1999_03
特許番号
US05876757

反応ノート

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