Benzene → Phenyl propenyl ketone

HRID 1428444ノート

反応式

HRID 1428444 の反応式
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:7](Cl)(=[O:11])/[CH:8]=[CH:9]/[CH3:10].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[C:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)(=[O:11])/[CH:8]=[CH:9]/[CH3:10]

参加物

5

反応物 3

HCID 241BenzeneHCID 643131trans-Crotonyl chlorideHCID 6451240Aluminum(III) Chloride

生成物 1

HCID 231934Phenyl propenyl ketone

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

Benzene (1 mL), crotonoyl chloride (236 mg), and aluminium chloride (280 mg) were reacted in dichloromethane (1.5 mL) at from −30° C. to room temperature for 16 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (66 mg).

後処理

  1. additionThe resultant was treated in the same manner

出典と根拠

ORDレコード
ord-a2c583fdae14416b98895aa44421cec9
出典データセット
uspto-grants-2015_01
特許番号
US08937091B2

反応ノート

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