化工社化工社 化学情報印刷レポート · 研究参考用
1-Bromo-2-nitrobenzene → 7-Methoxy-3-(2-nitrophenyl)-1,2-dihydronaphthalene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Bromo-2-nitrobenzene | HCID 11341 | — |
| 反応物 | Stannane, tributyl(2-nitrophenyl)- | HCID 11338886 | — |
| 反応物 | 6-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate | HCID 15330256 | — |
| 生成物 | 7-Methoxy-3-(2-nitrophenyl)-1,2-dihydronaphthalene | HCID 23087148 | — |
反応手順
Synthesized from 1-bromo-2-nitrobenzene according to an analogous synthetic method to Preparation Example 76, tributyl(2-nitrophenyl)tin (7.3 g) and 6-methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate (2.2 g) were used according to an analogous synthetic method to Preparation Example 77 to provide the title compound (1.5 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07612114B2 |
| 出典データセット | uspto-grants-2009_11 |
| ORD ID | ord-b32ce141dc53404ea6e4e18e82ce31b5 |
| 出典メモ | uspto-grants-2009_11 |