4-Ethenylphenyl acetate → Acetic acid 4-[2-(2-amino-4-methoxyphenyl)vinyl]phenyl ester

反応式

Br[C:2]1[CH:7]=[CH:6][C:5]([O:8][CH3:9])=[CH:4][C:3]=1[N+:10]([O-])=O.[C:13]([O:16][C:17]1[CH:24]=[CH:23][C:20]([CH:21]=[CH2:22])=[CH:19][CH:18]=1)(=[O:15])[CH3:14]>>[NH2:10][C:3]1[CH:4]=[C:5]([O:8][CH3:9])[CH:6]=[CH:7][C:2]=1[CH:22]=[CH:21][C:20]1[CH:23]=[CH:24][C:17]([O:16][C:13](=[O:15])[CH3:14])=[CH:18][CH:19]=1

参加物

反応物 2

HCID 758214-Ethenylphenyl acetate

HCID 792884-Bromo-3-nitroanisole

生成物 1

HCID 66627499Acetic acid 4-[2-(2-amino-4-methoxyphenyl)vinyl]phenyl ester

実験手順

Synthesized from 4-bromo-3-nitroanisole (2.3 g) and 4-acetoxystyrene (1.7 ml) according to an analogous synthetic method to Example 107, the title compound (1.2 g) was obtained.

出典と根拠

ORDレコード: ord-4212d5068d0a43659576a8087e6ec5ec
出典データセット: uspto-grants-2009_11
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07612114B2

反応ノート

読み込み中…