Cyclohexanone, 2-propyl- → Methyl 3-(1-methyl-2-oxocyclohexyl)propanoate

HRID 1438917

反応式

HRID 1438917 の反応式
CC1CCCCC1=O.C(C1CCCCC1=O)C.C(C1CCCCC1=O)CC.[CH3:28][O:29][C:30](=[O:42])[CH2:31][CH2:32][C:33]1([CH2:40]C)[CH2:38][CH2:37][CH2:36][CH2:35][C:34]1=[O:39].COC(=O)CCC1(CCC)CCCCC1=O>>[CH3:28][O:29][C:30](=[O:42])[CH2:31][CH2:32][C:33]1([CH3:40])[CH2:38][CH2:37][CH2:36][CH2:35][C:34]1=[O:39]

参加物

6

反応物 5

HCID 7199Cyclohexanone, 2-propyl-HCID 114192-MethylcyclohexanoneHCID 204742-EthylcyclohexanoneHCID 122918881-Ethyl-2-oxocyclohexanepropionic acid methyl esterHCID 227572861-Propyl-2-oxocyclohexanepropionic methyl ester

生成物 1

HCID 574325Methyl 3-(1-methyl-2-oxocyclohexyl)propanoate

実験手順

in the same manner but replacing 2-methylcyclohexanone with an equivalent amount of 2-ethylcyclohexanone or 2-propylcyclohexanone, 1-ethyl-2-oxocyclohexanepropionic acid methyl ester, bp 117° - 120° C/0.4mm, and 1-propyl-2-oxocyclohexanepropionic methyl ester, νmaxCHCl3 1735, 1700cm-1, are obtained, respectively.

後処理

  1. customνmaxCHCl3 1735, 1700cm-1, are obtained

出典と根拠

ORDレコード
ord-024b0687b64941429e696cf79681d3c6
出典データセット
uspto-grants-1977_11
特許番号
US04057559

関連ノート

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