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Thionyl Chloride → 1-(Chloromethyl)pyrene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 反応物 | 1-Pyrenemethanol | HCID 104977 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | 1-(Chloromethyl)pyrene | HCID 97581 | — |
反応手順
Thionyl chloride (15 mL, 200 mmol) was added dropwise to a suspension of 1-hydroxymethylpyrene (9.3 g, 40 mmol) in dry benzene (150 mL) at 0° C. and the mixture was stirred at room temperature overnight. Evaporation of the solvent under reduced pressure gave a creamy-white solid, m.p. 146°-148° C., yield: 9.6 g, 96%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05498549 |
| 出典データセット | uspto-grants-1996_03 |
| ORD ID | ord-81efd5c907df4757a011c283c9f9299a |
| 出典メモ | uspto-grants-1996_03 |