化工社化工社 化学情報印刷レポート · 研究参考用
5,6-Bis(phenylmethoxy)-1H-indole → 5,6-Dihydroxyindole
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 5,6-Bis(phenylmethoxy)-1H-indole | HCID 20920 | — |
| 反応物 | 5,6-Diacetoxyindole | HCID 3805883 | — |
| 触媒 | Iron | HCID 23925 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | 5,6-Dihydroxyindole | HCID 114683 | — |
反応手順
In a first stage, 5,6-diacetoxyindole and 5,6-dibenzyloxyindole are prepared by means of a cyclizing reduction. In the case of 5,6-dibenzyloxyindole the cyclizing reduction is carried out using iron in the presence of acetic acid. In a second stage, 5,6-dihydroxyindole is obtained:
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05498746 |
| 出典データセット | uspto-grants-1996_03 |
| ORD ID | ord-09fff855d438491f9b2d7b87c9222daf |
| 出典メモ | uspto-grants-1996_03 |