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Hydroquinone → Phenoxyethyl acrylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydroquinone | HCID 785 | — |
| 反応物 | Methyl Acrylate | HCID 7294 | — |
| 反応物 | 4-Methoxyphenol | HCID 9015 | — |
| 反応物 | Dimethyltin dichloride | HCID 12955 | — |
| 反応物 | Phenoxyethanol | HCID 31236 | — |
| 反応物 | Sodium Methoxide | HCID 10942334 | — |
| 溶媒 | Heptane | HCID 8900 | — |
| 生成物 | Phenoxyethyl acrylate | HCID 39485 | 91% |
反応手順
In a similar manner, a mixture of 414.5 parts 2-phenoxyethanol, 388 parts methyl acrylate, 141.6 parts heptane, 4.1 parts dimethyltin dichloride, 1.1 parts sodium methoxide (molar ratio 1.09:1), 1.4 parts 4-methoxyphenol and 0.5 parts hydroquinone yielded 524.8 parts (91 percent yield, based on 2-phenoxyethanol) of 2-phenoxyethyl acrylate with a purity of 98.3 percent, containing no detectable tin.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05498751 |
| 出典データセット | uspto-grants-1996_03 |
| ORD ID | ord-eddedbd113144e2cb3347d25eaf899dd |
| 出典メモ | uspto-grants-1996_03 |